Dua Lipa, Ava Max and former One Direction star Niall Horan will grace the stage during the annual ceremony, this year held in Seville, Spain.
The show will also feature performances by the likes of Halsey, Mabel and Spanish singer Rosalia.
Singer Ariana Grande is expected to be among the big winners at Sunday night’s star-studded MTV Europe Music Awards.
She is nominated seven times, including for the coveted best artist gong, as well as for best video for her hit song Thank You, Next.
But she faces stiff competition from newcomers Lil Nas X and Billie Eilish, who follow with six nominations each, while Colombian reggaeton star J Balvin takes five, including best artist.
This year’s edition will be hosted by US singer and actress Becky G, who takes over from last year’s host Hailee Steinfeld.
She will use the platform to perform Como No, her collaboration with Akon, live for the first time.
She joins the event’s star-studded list of former hosts, including Sir Tom Jones, Robbie Williams and Katy Perry.
Joining Green Day on the stage performing will be Dua Lipa, Halsey, Rosalía, Niall Horan, Akon, Ava Max, Mabel and NCT 127 too.
Liam Gallagher will also make an appearance to collect the inaugural rock icon award.
The ex-Oasis rocker is expected to perform one song from his new album Why Me? Why Not and one by his former band.
Here are the nominations in full
BEST VIDEO Ariana Grande – thank u, next, Billie Eilish – bad guy, Lil Nas X – Old Town Road (Remix) ft. Billy Ray Cyrus, ROSALÍA, J Balvin – Con Altura ft. El Guincho, Taylor Swift – ME! ft. Brendon Urie of Panic! At The Disco
BEST ARTIST Ariana Grande, J Balvin, Miley Cyrus, Shawn Mendes, Taylor Swift
BEST SONG Ariana Grande – 7 rings, Billie Eilish – bad guy, Lil Nas X- Old Town Road (Remix) ft. Billy Ray Cyrus, Post Malone, Swae Lee – Sunflower, Shawn Mendes, Camila Cabello – Señorita
BEST COLLABORATION BTS, Halsey – Boy With LuvLil Nas X, Billy Ray Cyrus – Old Town Road (Remix)Mark Ronson, Miley Cyrus – Nothing Breaks Like a Heart, ROSALÍA, J Balvin – Con Altura ft. El Guincho, Shawn Mendes, Camila Cabello – Señorita, The Chainsmokers, Bebe Rexha – Call You Mine
BEST NEW Ava Max, Billie Eilish, Lewis Capaldi, Lil Nas X, LizzoMabel
BEST POP Ariana Grande, Becky G, Camila Cabello, Halsey, Jonas Brothers, Shawn Mendes
BEST ROCK Green Day, Imagine Dragons, Liam Gallagher, Panic! At The Disco, The 1975
BEST HIP-HOP 21 Savage, Cardi BJ, Cole, Nicki Minaj,Travis Scott
BEST ALTERNATIVEFKA TwigsLana Del Rey, Solange, twenty one pilots, Vampire Weekend
BEST ELECTRONIC Calvin Harris, DJ Snake, Marshmello, Martin Garrix, The Chainsmokers
BEST LOOK Halsey, J Balvin, Lil Nas X, Lizzo ROSALÍA
BIGGEST FANS Ariana Grande, Billie Eilish, BTS, Shawn Mendes, Taylor Swift
BEST WORLD STAGE Bebe Rexha, Isle of MTV Malta 2019, Hailee Steinfeld, Isle of MTV Malta 2018, Muse, Bilbao, Spain 2018, The 1975, Lollapalooza Paris Festival 2019, twenty one pilots, Lollapalooza Paris Festival 2019
BEST UK & IRELAND ACT Ed Sheeran, Lewis Capaldi, Little Mix, Mabel
The red carpet pre-show will also feature performances by the likes of Mexican pop star Sofia Reyes, Puerto Rican artist Jhay Cortez and Brazilian drag queen Pabllo Vittar.
The event is returning to Spain for a fourth time after visiting Barcelona in 2002, Madrid in 2010 and Bilbao in 2018.
The MTV EMAs airs live from the FIBES Conference and Exhibition Centre in Seville, Spain, on Sunday November 3 at 8pm on MTV.
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